Rapid determination of thiabendazole in orange extract using excitation-emission matrix fluorescence and second-order calibration based on alternating trilinear decomposition/alternating normalization-weighted error algorithms  

作　　者：WANG XueMei WU HaiLong NIE JinFang LI YuanNa YU YongJie YU RuQin 

机构地区：[1]State Key Laboratory of Chemo/Biosensing and Chemometrics,Hunan University,Changsha 410082,China

出　　处：《Science China Chemistry》2008年第8期729-735,共7页中国科学（化学英文版）

基　　金：Supported by the National Natural Science Foundation of China (Grant Nos. 20775025 and 20435010);973 Advanced Research Project (Grant No. 2007CB- 216404)

摘　　要：A novel approach is proposed for direct quantitative analysis of thiabendazole in the orange extract by using excitation-emission matrix fluorescence coupled with second-order calibration methods based on the alternating trilinear decomposition(ATLD) and the alternating normalization-weighted error(ANWE) algorithms,respectively. The average recoveries of thiabendazole in the orange extract by using ATLD and ANWE with an estimated component number of two were 99.7 ± 3.3% and 103.5 ± 4.1%,respectively. Furthermore,the accuracy of the two algorithms was also evaluated through elliptical joint confidence region(EJCR) tests as well as figures of merit,such as sensitivity(SEN),selectivity(SEL) and limit of detection(LOD). The experimental results demonstrate that both algorithms have been satisfactorily applied to the determination of thiabendazole in orange extract,and the perform-ance of ANWE is slightly better than that of ATLD.A novel approach is proposed for direct quantitative analysis of thiabendazole in the orange extract by using excitation-emission matrix fluorescence coupled with second-order calibration methods based on the alternating trilinear decomposition (ATLD) and the alternating normalization-weighted error (ANWE) algorithms, respectively. The average recoveries of thiabendazole in the orange extract by using ATLD and ANWE with an estimated component number of two were 99.7 ± 3.3% and 103.5 ± 4.1%, respectively. Furthermore, the accuracy of the two algorithms was also evaluated through elliptical joint confidence region (EJCR) tests as well as figures of merit, such as sensitivity (SEN), selectivity (SEL) and limit of detection (LOD). The experimental results demonstrate that both algorithms have been satisfactorily applied to the determination of thiabendazole in orange extract, and the performance of ANWE is slightly better than that of ATLD.

关 键 词：excitation-emission matrix fluorescence ALTERNATING trilinear decomposition ALTERNATING normalization-weighted error ORANGE EXTRACT THIABENDAZOLE 

分 类 号：TP301[自动化与计算机技术—计算机系统结构]