Synthesis and Characterization of Lanthanide Complexes Involving Cyclopentadienyl and Benzohydroximic Acid Ligand  

作　　者：王修然 万玉保 胡继萍 

出　　处：《Journal of Rare Earths》2000年第4期315-317,共3页稀土学报（英文版）

基　　金：ProjectsupportedbytheNaturalScienceFoundationoftheEducationCommitteeofAnhuiProvince (97J0 42 )

摘　　要：By the reaction of Cp 3Ln with HL(Cp=η 5 C 5H 5, cyclopentadienyl; Ln=Yb, Tm, Er, Ho, Dy, Gd, Pr; HL=benzohydroximic acid), seven new complexes of the general formula Cp 2LnL were synthesized. All the complexes were characterized by elemental analysis, infrared spectra, and mass spectra. Based on these data, the probable structure was proposed.By the reaction of Cp 3Ln with HL(Cp=η 5 C 5H 5, cyclopentadienyl; Ln=Yb, Tm, Er, Ho, Dy, Gd, Pr; HL=benzohydroximic acid), seven new complexes of the general formula Cp 2LnL were synthesized. All the complexes were characterized by elemental analysis, infrared spectra, and mass spectra. Based on these data, the probable structure was proposed.

关 键 词：rare earths benzohydroximic acid lanthanide complexes SYNTHESIS 

分 类 号：O614[理学—无机化学]