Inclusion property and Diels-Alder reaction of bis (diphenylphosphine oxide) butadiyne  

作　　者：李明霞 李金亮 王永梅 孟继本 

机构地区：[1]Department of Chemistry, Nankai University, Tianjin 300071, China

出　　处：《Chinese Journal of Chemistry》2000年第3期373-376,共4页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China (No. 29572054) and the Natural Science Foundation of Tianjin (No. 963604711).

摘　　要：The host molecule, bis (diphenylphosphine oxide) butadiyne (2), includes a variety of guests to form five complexes (2a—2e). In addition, the Diels-Alder reaction between 2 and anthracene gives 9, 9′, 10, 10′-tetrahedron-9, 9′, 10, 10′-bi-ethenoantracene-11, 11′-bis (diphenylphosphine oxide) (3) which is a potential di-π-methane reactant and can undergo photorearrangement.The host molecule, bis (diphenylphosphine oxide) butadiyne (2), includes a variety of guests to form five complexes (2a—2e). In addition, the Diels-Alder reaction between 2 and anthracene gives 9, 9′, 10, 10′-tetrahedron-9, 9′, 10, 10′-bi-ethenoantracene-11, 11′-bis (diphenylphosphine oxide) (3) which is a potential di-π-methane reactant and can undergo photorearrangement.

关 键 词：INCLUSION Diels-Alder reaction phosphine oxide solid-state reaction 

分 类 号：O621[理学—有机化学]