Synthesis of novel poly(aryl ether amide)s containing the phthalazinone moiety  

作　　者：程琳 蹇锡高 

机构地区：[1]Department of Materials Engineering, Wuhan Institute of Chemical Technology, Wuhan, Hubei 430074, China [2]Department of Polymer Science & Materials , Dalian University of Technology, Dalian, Liaoning 116012 , China

出　　处：《Chinese Journal of Chemistry》2000年第3期414-417,共4页中国化学（英文版）

基　　金：Project (No. 59473019) supported by the National Natural Science Foundation of China.

摘　　要：Two novel heterocylic diamine monomers: l,2-dihydro-2-(4-aminophenyl)-4-4-(4-aminophenoxy) phenyl]-(2H)-phthalazin-l-one and 1,2-Dihydro-2-( 4-aminophenyl )-4-[4-(4-aminophenoxy-3, 5-dimethylphenyl]-(2H)-phthalazin-1-one were successfully synthesized using readily available heterocyclic bisphenol-like monomers through two steps in high yield. A series of novel poly(aryl ether amide)s containing the phthalazinone moiety with inherent viscosities of 1.16–1.67 dL/g were prepared by the direct polymerization of the novel diamines and aromatic dicarboxylic acids using triphenyl phosphite and pyridine as condensing agents. The polymers were readily soluble in a variety of solvents such as N,N -dimethylformamide (DMF), N,N-dimethylacetamide (DMAc), dimethylsulfoxide ( DMSO ), N-methyl-2-pyrrolidinone (NMP), and pyridine. The polymers had high glass transition temperatures ( Tg) in the 291–329°C range.Two novel heterocylic diamine monomers: l,2-dihydro-2-(4-aminophenyl)-4-4-(4-aminophenoxy) phenyl]-(2H)-phthalazin-l-one and 1,2-Dihydro-2-( 4-aminophenyl )-4-[4-(4-aminophenoxy-3, 5-dimethylphenyl]-(2H)-phthalazin-1-one were successfully synthesized using readily available heterocyclic bisphenol-like monomers through two steps in high yield. A series of novel poly(aryl ether amide)s containing the phthalazinone moiety with inherent viscosities of 1.16–1.67 dL/g were prepared by the direct polymerization of the novel diamines and aromatic dicarboxylic acids using triphenyl phosphite and pyridine as condensing agents. The polymers were readily soluble in a variety of solvents such as N,N -dimethylformamide (DMF), N,N-dimethylacetamide (DMAc), dimethylsulfoxide ( DMSO ), N-methyl-2-pyrrolidinone (NMP), and pyridine. The polymers had high glass transition temperatures ( Tg) in the 291–329°C range.

关 键 词：Poly(aryl ether amide) PHTHALAZINONE heterocyclic diamine direct polymerization 

分 类 号：O631[理学—高分子化学]