Asymmetric Transfer Hydrogenation of Ketone Catalyzed by Novel Ru(Ⅱ)-Chiral Sulfonamide Complex  

作　　者：Chun E DONG Jun Long ZHANG Wei Zhong ZHENG Zuo Long YU Liang Fu ZHANG (Chengdu Institute of organic Chemistry Academ Sinica. Chengdu 610041) 

出　　处：《Chinese Chemical Letters》2000年第5期383-384,共2页中国化学快报（英文版）

基　　金：This research was supported by Hong Kong Polytech University.

摘　　要：Two new chiral Ru(Ⅱ)-sulfonamide complex have been used to catalyze the enantioselective transfer hydrogenation of prochiral ketones and the secondary alcohols are obtained with good to excellent optical yields.Two new chiral Ru(Ⅱ)-sulfonamide complex have been used to catalyze the enantioselective transfer hydrogenation of prochiral ketones and the secondary alcohols are obtained with good to excellent optical yields.

关 键 词：SULFONAMIDE transfer hydrogenation. 

分 类 号：O614.8[理学—无机化学]