Synthesis and Crystal Structure of [NiL_2(H_2O)_2](ClO_4)_2L=MBPT=4-P-methylphenyl-3,5-bis-(pyridin-2-yl)-1,2,4-triazole  

Synthesis and Crystal Structure of [NiL_2(H_2O)_2](ClO_4)_2 L=MBPT=4-P-methylphenyl-3,5-bis-(pyridin-2-yl)-1,2,4-triazole

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作  者:Si Chang SHAO Dun Ru ZHU Tian Wei WANG Yong ZHANG S. Shanmuga Sundara RAJ, Hoong Kun FUN (Coordination Chemistry Institute & State Key Laboratory of Coordination Chemistry. Nanjing University, Nanjing 210093 X-ray Crystallography Unit, School of physi 

出  处:《Chinese Chemical Letters》2000年第1期93-94,共2页中国化学快报(英文版)

摘  要:The Nickel (II) complex, [Ni(MBPT)_2(H_2,O)_2],](C1O-(4-2), (MBPT=4-p-methylphenyl-3.5- 3,5 bis- (pyridin -2 -y1)-1, 2, 4-triazo1e). was synthesized and its crystal structure determined by X-ray diffraction methods.The complex adopts a distorted octahedral environment made up of two bidentate chelating MBPT ligands in the equatorial plane and two water molecules filling the axial positions.The Nickel (II) complex, [Ni(MBPT)_2(H_2,O)_2],](C1O-(4-2), (MBPT=4-p-methylphenyl-3.5- 3,5 bis- (pyridin -2 -y1)-1, 2, 4-triazo1e). was synthesized and its crystal structure determined by X-ray diffraction methods.The complex adopts a distorted octahedral environment made up of two bidentate chelating MBPT ligands in the equatorial plane and two water molecules filling the axial positions.

关 键 词:Nickel complex crystal structure triaryltriazole. 

分 类 号:O627[理学—有机化学]

 

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