相转移催化法合成邻氯苯乙腈  

Phase Transfer Catalytic Synthesis of Ortho chlorophenylacetonitrile

作　　者：胡在君[1] 唐薰[1] 刘鑫[1] 张宏生[1] 

机构地区：[1]湖南大学化学化工学院

出　　处：《湖南大学学报（自然科学版）》1999年第S1期16-18,27,共4页Journal of Hunan University:Natural Sciences

基　　金：湖南省科委资助

摘　　要：采用三乙胺为相转移催化剂，以邻氯氯苄和氰化钠为原料合成邻氯苯乙腈．研究了应用相转移催化剂合成邻氯苯乙腈的各种影响因素．在适宜条件下，邻氯苯乙腈的收率可达９５．８％．Ortho chlorophenylacetonitrile was synthesized from o chlorobenzyl chloride and sodium cyanide with triethylamine as phase transfer catalyst.The influence of various factors in the reaction were studied.The yield of o chlorophenylacteonitrile was 95.8 % under proper conditions.

关 键 词：邻氯氯苄 邻氯苯乙腈 氰化钠相转移催化剂 

分 类 号：O625.29[理学—有机化学]