Thermal Decomposition Kinetics of Ni(Ⅱ)Complex with Norfloxacin  

Thermal Decomposition Kinetics of Ni() Complex with Norfloxacin

作　　者：张建军 戴玉杰 张秀利 陈会兰 葛立国 周清泽 

出　　处：《Rare Metals》1999年第2期58-63,共6页稀有金属（英文版）

摘　　要：The thermal decomposition of the 2H2O (NFA=C16H18FN3O3, norfloxacin) and its kinetics were studied under the nonisothermal condition in nitrogen by TGDTG and DTA methods. The intermediate and residue for each decomposition were identified from TG curve. The Achar method and the MadhusudananKrishnanNinan (MKN) method were used to analyze the nonisothermal kinetic data. The possible reaction mechanisms were investigated by comparing the kinetic parameters. The kinetic equation for the third stage and the mathematical expressions for the kinetic compensation effects of the third stage were obtained.The thermal decomposition of the 2H2O (NFA=C16H18FN3O3, norfloxacin) and its kinetics were studied under the nonisothermal condition in nitrogen by TGDTG and DTA methods. The intermediate and residue for each decomposition were identified from TG curve. The Achar method and the MadhusudananKrishnanNinan (MKN) method were used to analyze the nonisothermal kinetic data. The possible reaction mechanisms were investigated by comparing the kinetic parameters. The kinetic equation for the third stage and the mathematical expressions for the kinetic compensation effects of the third stage were obtained.

关 键 词：Thermal decomposition Nonisothermal kinetics Mechanisms Ni() Complex NORFLOXACIN 

分 类 号：O614.813[理学—无机化学]