Reaction of diaminoglyoxime and cyclic azine compounds in high temperature and pressure water  

作　　者：T.B.Brill 

出　　处：《Chinese Science Bulletin》1998年第16期1395-1399,共5页

基　　金：ThisworkwassupportedbytheK .G .WangFoundationofHongKong

摘　　要：Diaminoglyoxime was reacted in water at 150-400℃ and at 27.5 MPa pressure in metal Ti tubing reactor. Experimental results indicate that, diaminoglyoxime can be converted into NH-3 and CO-2, either through direct hydrolysis or through pyrolysis and polymerization, and then further hydrolysis. The possible reaction mechanism is nucleophilic addition of water.Diaminoglyoxime was reacted in water at 150–400°C and at 27.5 MPa pressure in metal Ti tubing reactor. Experimental results indicate that, diaminoglyoxime can be converted into NH3 and CO2, either through direct hydrolysis or through pyrolysis and polymerization, and then further hydrolysis. The possible reaction mechanism is nucleophilic addition of water.

关 键 词：diaminoglyoxime CYCLIC AZINE compound SUPERCRITICAL WATER pyrolysis HYDROLYSIS organic wastes. 

分 类 号：P594[天文地球—地球化学]