Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate: Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles  

作　　者：Song Lin ZHANG and Yong Min ZHANG(Department of Chemistry, Hangzhou University, Hangzhou, 310028) 

出　　处：《Chinese Chemical Letters》1998年第10期885-887,共3页中国化学快报（英文版）

摘　　要：The Se-St bond in arylselenotrimethylsilane was reduced by samarium diiodide to produce samarium arylselenolate, which reacted with a,β-unsaturated esters or α,β-unsaturated nitriles to give β-selenoesters and β-selenonitriles, respectively.The Se-St bond in arylselenotrimethylsilane was reduced by samarium diiodide to produce samarium arylselenolate, which reacted with a,β-unsaturated esters or α,β-unsaturated nitriles to give β-selenoesters and β-selenonitriles, respectively.

关 键 词：samarium diiodide arylselenotrimethylsilane arylseleno esters arylseleno nitriles 

分 类 号：O614[理学—无机化学]