The Isomerization/Chlorination of O,O-Diallyl Thiophosphoric (-nic) Acid Esters with Phosphorus Oxychloride─A New Convenient Method for Synthesis of S-Alkyl Thiophosphoric(-nic) Acid Derivatives  

作　　者：Zheng Jie HE Ju Xiang LIU Zheng Hong ZHOU and Chu Chi TANG(State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071) 

出　　处：《Chinese Chemical Letters》1998年第10期903-905,共3页中国化学快报（英文版）

摘　　要：The isomerization/chlorination of O, O-diallyl thiophosphoric (-nic) acid esters with phosphrus oxychloride gives S-allyl thiophosphoro (-no)chloride, which reacts with subsittuted phenol in chloroform in the presence of triethylamine to afford eighteen new S-allyl thiophosphoric(-nic) acid derivatives. Thus, a new convenient method has been provided for synthesis of the title compounds.The isomerization/chlorination of O, O-diallyl thiophosphoric (-nic) acid esters with phosphrus oxychloride gives S-allyl thiophosphoro (-no)chloride, which reacts with subsittuted phenol in chloroform in the presence of triethylamine to afford eighteen new S-allyl thiophosphoric(-nic) acid derivatives. Thus, a new convenient method has been provided for synthesis of the title compounds.

关 键 词：ISOMERIZATION CHLORINATION phosphoro(-no)thionate phosphoro(-no)thiolate phosphoro (-no) chlorothiolate phosphorus oxychloride 

分 类 号：O621[理学—有机化学]