Diels-Alder Reactions of 3-Carboethoxy- and 3-Carbonitrile-2-Cyclohexen-1-one  

作　　者：Wen Qian YANG Shi Zhi CHEN Liang HUANG(Institute of Materia Medica, Chinese Academy of Medical Sciences & Peking Union MedicalCollege Beijing 100050) 

出　　处：《Chinese Chemical Letters》1998年第3期233-234,共2页中国化学快报（英文版）

摘　　要：Aluminum chloride induced Diels-Alder reactions of 3-carboethoxy- and 3-carbonitrile-2-cyclohexen-1-one with cyclopentadiene, isoprene and (E)-piperylene were described. Thestereochemistry of the adducts were confirmed by 2D-NMR spectroscopy and isomerizationreactions.Aluminum chloride induced Diels-Alder reactions of 3-carboethoxy- and 3-carbonitrile-2-cyclohexen-1-one with cyclopentadiene, isoprene and (E)-piperylene were described. Thestereochemistry of the adducts were confirmed by 2D-NMR spectroscopy and isomerizationreactions.

关 键 词：Diels-Alder reaction base-induced isomerization 

分 类 号：O621[理学—有机化学]