固-液相转移催化N-烷化合成2,6-二(二烷氨基)蒽醌的研究  

Study on N-Alkylation of 2, 6-Diamino Anthraquinone Under Solid-Liquid PTC

作　　者：高建荣[1] 陈兴[2] 程侣柏[2] 

机构地区：[1]浙江工业大学化学工程学院,杭州310032 [2]大连理工大学精细化工国家重点实验室,大连116012

出　　处：《浙江工业大学学报》1998年第2期114-117,共4页Journal of Zhejiang University of Technology

基　　金：国家自然科学基金

摘　　要：根据固-液相转移催化原理，由2，6-二氨基蒽醌经固-液相转移催化N-烷化合成了4种2，6-二（二烷氨基）蒽醌。产品单程收率达60％-67％。该类材料可能成为有价值的三阶非线性光学材料。Based on the principle of solid-liquid phase transfer catalysis , 4 products of 2, 6- bis(dialkylamino ) anthraquinone were prepared by solid-liquid phase transfer catalysis N-alkylation of 2, 6-diamino anthraquinone . The yields were 60% ~ 67% respectively. The material may be one applicable kind of the third-order nonlinear optical matrials.

关 键 词：相转移催化 N-烷化 烷氨基蒽醌 非线性光学 

分 类 号：O625[理学—有机化学]