AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅧ. THE POLYMERIZATION KINETICS OF BENZONITRILE CATALYZED BY METAL ACETYLACETONATE  

AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅧ. THE POLYMERIZATION KINETICS OF BENZONITRILE CATALYZED BY METAL ACETYLACETONATE

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作  者:秦伟 黄志镗 

机构地区:[1]Institute of Chemistry, Academia Sinica, Beijing 100080

出  处:《Chinese Journal of Polymer Science》1993年第3期273-278,共6页高分子科学(英文版)

摘  要:The bulk polymerization of benzonitrile catalyzed by Co(Ⅱ), Co(Ⅲ) and Fe(Ⅲ) acetylacetonate was studied. The results of kinetics study show that the rate of polymerization was proportional to first power of the concentration of catalyst and second power of the concentration of monomer.The bulk polymerization of benzonitrile catalyzed by Co(Ⅱ), Co(Ⅲ) and Fe(Ⅲ) acetylacetonate was studied. The results of kinetics study show that the rate of polymerization was proportional to first power of the concentration of catalyst and second power of the concentration of monomer.

关 键 词:BENZONITRILE Metal acetylacetonate Catalyst Polymerization. 

分 类 号:O63[理学—高分子化学]

 

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