Tetrahydrofolate coenzyme models I·Synthesis of l-methyl-2-phenyl-3-aryl imidazoliniumiodide and benzylildyne(phenyl-substitutef one carbon unit)transfer reactions  

作　　者：XIA, Chi-Zhong ZHOU, Pei-Wen DING, Jing-Fan The Institute of Molecular Science, Department of Chemistry,Shanxi University, Taiyuan, 030006 

出　　处：《Chinese Journal of Chemistry》1990年第4期333-339,共10页中国化学（英文版）

基　　金：This work was supported by the Science Foundation of Shanxi Province.

摘　　要：Four 1, 2, 3-trisubstituted imidazolinium iodides which were used as 5,10-^+CPh-THF model (7-10) at formic acid oxidation level were synthesized. The benzylidyne group (phenyl- substituted one carbon unit)transfer reactions from these compounds to Grignard reagent were in- vestigated, and the reactions of these compounds with KBH_4 and NaOH were also studied.Four 1, 2, 3-trisubstituted imidazolinium iodides which were used as 5,10-^+CPh-THF model (7-10) at formic acid oxidation level were synthesized. The benzylidyne group (phenyl- substituted one carbon unit)transfer reactions from these compounds to Grignard reagent were in- vestigated, and the reactions of these compounds with KBH_4 and NaOH were also studied.

关 键 词：Synthesis of l-methyl-2-phenyl-3-aryl imidazoliniumiodide and benzylildyne Tetrahydrofolate coenzyme models I phenyl-substitutef one carbon unit)transfer reactions 

分 类 号：O6[理学—化学]