STUDY ON BINUCLEAR COPPER(I)COMPLEXES III.SYNTHESIS,CHARACTERIZATION AND ELECTROCHEMISTRY OF DICHLORO-TRIS(4-VINYLPYRIDINE)-DICOPPER(I)COMPLEX  

作　　者：Zhen Feng XI Rui Na YANG Dou Man JIN Henan Institute of Chemistry,Zhengzhou 450003 

出　　处：《Chinese Chemical Letters》1990年第2期185-186,共2页中国化学快报（英文版）

摘　　要：Recent years,many novel complexes have been prepared by using hetero-bidentate ligands.However,complexes with such ligands as 4-vinylpyridine which has two different coordinating sites have not been reported,and only a few complexes of Cu(I)have been published^(1-3).The title complex Cu_2(C_5H_4N·CH=CH_2)_3Cl was prepared and characterized by elemental analyses,ICP,IR,and electronic spectra.Its conductivity,oxidation potential and reduction potential were measured.Recent years,many novel complexes have been prepared by using hetero-bidentate ligands.However,complexes with such ligands as 4-vinylpyridine which has two different coordinating sites have not been reported,and only a few complexes of Cu(I)have been published^(1-3).The title complex Cu_2(C_5H_4N·CH=CH_2)_3Cl was prepared and characterized by elemental analyses,ICP,IR,and electronic spectra.Its conductivity,oxidation potential and reduction potential were measured.

关 键 词：I)COMPLEXES III.SYNTHESIS CHARACTERIZATION AND ELECTROCHEMISTRY OF DICHLORO-TRIS STUDY ON BINUCLEAR COPPER I)COMPLEX DICOPPER VINYLPYRIDINE Cu CI III 

分 类 号：O6[理学—化学]