MOLECULAR VOLUMES OF SALTS. WITH TRIANGULAR RADICALS  

作　　者：张金民 叶大年 

机构地区：[1]Institute of Geology, Academia Sinica Beijing 100011, PRC

出　　处：《Science China Chemistry》1990年第4期485-494,共10页中国科学（化学英文版）

基　　金：Project supported by the National Natural Science Foundation of China.

摘　　要：The present paper discusses some characteristics of the molecular volumes of carbonates, nitrates and borates. It confirms that the molecular volume of H_2O in the hydrates of this kind of salts approximates to a constant. When the coordination numbers of cations in mixed salts are identical with those in the single salts, the additivity of the molecular volume is quite accurate. Over 100 sets of data demonstrate that a general additivity is true, the average relative error being ±2.31%. The concept of the topological molecular volume is proposed based, on the additivity. For salts with the same radical and equally charged cations, the molecular volume varies linearly with the cation radius. The volume effects of CO_3^(2-) NO_3^- and BO_3^(3-) in packing can be obtained by extrapolation. They are equal to a large sphere whose volume is the sum of those of three O^(2-). This paper also discusses the possibility of compiling a table of ionic volumes.The present paper discusses some characteristics of the molecular volumes of carbonates, nitrates and borates. It confirms that the molecular volume of H₂O in the hydrates of this kind of salts approximates to a constant. When the coordination numbers of cations in mixed salts are identical with those in the single salts, the additivity of the molecular volume is quite accurate. Over 100 sets of data demonstrate that a general additivity is true, the average relative error being ±2.31%. The concept of the topological molecular volume is proposed based, on the additivity. For salts with the same radical and equally charged cations, the molecular volume varies linearly with the cation radius. The volume effects of CO₃^2- NO₃^- and BO₃^3- in packing can be obtained by extrapolation. They are equal to a large sphere whose volume is the sum of those of three O^2-. This paper also discusses the possibility of compiling a table of ionic volumes.

关 键 词：CARBONATE nitrate BORATE molecular volume additivity. 

分 类 号：O6[理学—化学]