有机模板固相合成磷酸锌及其表征  

Solid-State Synthesis of Zincophosphate with Organic Temple and Its Characterization

作　　者：王金霞[1] 高艳阳[1] 魏宁[1] 

机构地区：[1]中北大学理学院化学系,山西太原030051

出　　处：《化学与生物工程》2011年第11期35-36,61,共3页Chemistry & Bioengineering

基　　金：中北大学校科学基金资助项目

摘　　要：以1,6-己二胺作为模板剂,以ZnCl2、NaH2PO4为原料,采用固相合成法于80℃反应4 h合成了含有模板剂的磷酸锌化合物3C6N2H18.[Zn5H(PO4)4]2.6H2O,产物用化学分析、元素分析、红外光谱及热重分析等进行了表征。结果表明,用固相合成法能够在低温、短时间内合成磷酸锌化合物。Using 1,6-diaminohexane as template agent,zincophosphate compound 3C6N2H18·[Zn5H（PO4）4]2·6H2O was prepared through reacting at 80 ℃ for 4 h by solid-state synthesis method with ZnCl2 and NaH2PO4 as raw materials.The prouduct was characterized by IR and TG analysis.The results showed that zincophosphate compound could be synthesized by solid-state method at lower heating temperature in shorter time.

关 键 词：模板 固相合成 磷酸锌 表征 

分 类 号：TQ132.41[化学工程—无机化工] O614.24[理学—无机化学]