植物释放挥发性有机物(BVOC)向二次有机气溶胶(SOA)转化机制研究  

Study on Transformation Mechanism of SOA from Biogenic VOC Under UV-B Condition

作　　者：李莹莹[1] 李想[1] 陈建民[1] 

机构地区：[1]复旦大学环境科学与工程系,上海200433

出　　处：《环境科学》2011年第12期3588-3592,共5页Environmental Science

基　　金：高等学校博士学科点专项科研基金项目(20070246029);国家自然科学基金项目(21177025)

摘　　要：利用自制玻璃生态罩,研究植物挥发性有机物(BVOC)的释放机制.在紫外光诱导条件下,BVOC经历一系列的光氧化反应,最终产生了二次有机气溶胶(SOA).运用固相微萃取(SPME)和气相色谱-质谱联用(GC-MS)技术,对目标植物(驱蚊草)释放出的BVOC进行采样分析,共检测出7种主要化合物,其中主要为单萜类、倍半萜类、醇类和酮类物质.研究发现,在紫外光的照射下,这些BVOC可以发生光氧化反应转化为SOA.利用串联差分淌度分析仪(TDMA)测定SOA的粒径分布和SOA颗粒物的吸湿性.结果表明粒径范围大致是50～320 nm,吸湿性研究发现这些SOA具有吸湿性,生长因子可以从1.05增长到1.11.A laboratory study was carried out to investigate the biogenic volatile organic compounds（BVOC） in a lab-made glass chamber.The secondary organic aerosol（SOA） products can be detected under the UV photooxidation of BVOC.Pelargonium × Citrenella was chosen as the target plant in this research because it can release a large amount of BVOCs.The predominant 7 alkene and ketol compounds were detected by using solid phase microextraction（SPME） sampling and gas chromatography/mass spectrometry（GC/MS） analysis.The photochemical experiment indicated that these BVOC can be rapidly oxidized into SOA under UV-B irradiation.A tandem differential mobility analyzer（TDMA） was used to measure the size distribution and the hygroscopicity of the SOA.The particle diameter was in the range of 50 nm to 320 nm.The high hygroscopicity of SOA was also obtained and the size increased from 1.05 to 1.11 during the wet experiment.

关 键 词：二次有机气溶胶 挥发性有机物 驱蚊草 固相微萃取 气相色谱质谱 

分 类 号：X511[环境科学与工程—环境工程]