手性导电高分子聚合物的研究进展  

Progress in Chiral Conducting Polymers

作　　者：杨丰科[1] 曹伟丽[1] 李金芝[1] 

机构地区：[1]青岛科技大学化学化工学院,青岛266042

出　　处：《材料导报》2011年第21期136-139,145,共5页Materials Reports

基　　金：山东省自然科学基金(Q2006B02);兰州大学功能有机分子国家重点实验室开放基金(200708)

摘　　要：手性导电高分子聚合物在手性高分子领域里有很多独特的化学性质,已成为功能材料领域的研究热点。综述了聚苯胺、聚吡咯和聚噻吩等一些经典手性导电高分子聚合物的合成途径:当共轭的导电聚合物链上带有对映体纯取代基或有手性的掺杂阴离子时,其光学活性可以被π-π*电子吸收带所诱导;阐述了它们的合成发展史、现状、显著特性及手性导电高聚合物的应用前景。Chiral conducting polymers have many unique chemical properties in the field of chiral polymers, and have become a hot research in the field of functional materials. The synthesis way of the polyaniline, polypyrrole, polythiophene and some classical chiral conductive polymers are reviewed： when the conjugated conductive polymer chain have pure enantiomers of chiral substituents, or the doping anion , their optical activity can be π -π ＊ electronic absorption band induced. The history of their synthesis and current situation, significant characteristics and their prospects are reviewed.

关 键 词：手性导电高分子聚合物 聚苯胺 聚吡咯 聚噻吩 合成发展 应用前景 

分 类 号：TQ317.9[化学工程—高聚物工业]