巯基-烯光聚合制备交联网络聚合物的研究进展  

Research Progress in Preparation of Thiol-Ene Photopolymerization Network Polymer

作　　者：刘清[1] 张秋禹[1] 周健[1] 张和鹏[1] 

机构地区：[1]西北工业大学理学院应用化学系,西安710129

出　　处：《材料导报》2011年第21期140-145,共6页Materials Reports

基　　金：国家自然基金(50773063);973专项(2010CB635111)

摘　　要：巯基-烯光聚合体系是近年来发展的一种制备交联网络聚合物的新方法。介绍了用于制备交联网络聚合物的多官能团硫醇和烯类单体的发展及研究现状,概括了巯基-烯光聚合体系的主要特点,综述了巯基-烯/杂化光聚合体系的研究进展以及巯基-烯光聚合体系在涂料、胶黏剂、生物材料和光学材料等领域的研究现状,同时展望了巯基-烯光聚合体系的应用前景。Thiol-ene photopolymerization is an efficient technology to formulate networking polymer for several decades. Multifunctional thiol compounds are introduced, palying an important role in the networking as a coss-linker. The main features of the thiol-ene photopolymerization and thiol-ene/cation hybrid phtotcurable formulations are summarized. The applications of thiol-ene photocurahle networking polymer in coating, cementing compound, hoimaterials and optical materials are reviewed. In the end, the problems existing and the potential applicable fields are pointed.

关 键 词：巯基-烯 交联网络聚合物 氧阻聚 收缩率 胶黏剂 

分 类 号：TQ323.3[化学工程—合成树脂塑料工业]