对称联苯型环氧树脂的合成  

Synthesis of a symmetrical epoxy resin containing biphenyl structure

作　　者：张鹏云 陈卫东[2] 杨文龙[2] 李春新 刘茵 

机构地区：[1]甘肃省化工研究院,甘肃省兰州市730020 [2]西北师范大学化学化工学院生态环境相关高分子材料教育部重点实验室,甘肃省兰州市730070

出　　处：《合成树脂及塑料》2011年第6期34-36,共3页China Synthetic Resin and Plastics

基　　金：甘肃省科技厅科技支撑计划(0804GKCA019)

摘　　要：以3,3′,5,5′-四甲基联苯二酚和2-氯乙醇为原料合成3,3′5,5′-四甲基联苯二羟乙基醚,再通过环氧氯丙烷法合成对称联苯型环氧树脂:4,4′-双(2-羟基乙基)-3,3′,5,5′-四甲基联苯二缩水甘油醚(BP1)。用傅里叶变换红外光谱和核磁氢谱表征了产物结构,用差示扫描量热法研究了BPI的非等温固化行为,用扫描电子显微镜研究了BPl的形态结构。4,4′-二氨基二苯甲烷比对苯二胺更适合作BP1的固化剂,加入固化剂后,BP1的韧性提高。3,3＇ ,5,5＇ -tetramethyl-di（2-hydroxyethanyoxy）-biphenyl was synthesized from 3,3＇ ,5,5＇ - tetramethyl-diphenol and 2-chloroethanol and then, the resultant was taken as a precursor to further prepare a symmetrical epoxy resin containing biphenyl structure-4,4＇-bis （2_hydroxylethyl）-3,3＇,5,5＇-tetramethylbiphenyl （BP1）-via epichlorohydrin method. The structure, morphology and non-isothermal curing behavior of BP1 were characterized by Fourier transform infrared spectroscopy（FTIR）, hydrogen nuclear magnetic resonance （^1H-NMR）, scanning electron microscope（SEM） and differential scanning calorimetry（DSC）. The results show that 4,4＇-diaminodiphenylmethane（DDM） is a curing agent more appropriate for BP1 than p-phenylenediamine. The toughness of BP1 is improved greatly after the addition of the curing agents.

关 键 词：环氧树脂 3 3’ 5 5’-四甲基联苯二酚 固化 合成 

分 类 号：TQ323.5[化学工程—合成树脂塑料工业]