盐酸柳叶水甘草碱晶体结构解析  

Crystal Structure Determination of Hydrochloride Tabersonine from Powder X-ray Diffraction Data

作　　者：刘海峰[1] 王佳黎[1] 郭萍[1] 杨建华[1] 李晖[1] 

机构地区：[1]四川大学化学工程学院,四川成都610065

出　　处：《四川大学学报（工程科学版）》2011年第6期203-205,219,共4页Journal of Sichuan University (Engineering Science Edition)

摘　　要：从非洲伏康树籽提取出盐酸柳叶水甘草碱,经纯化、重结晶,获得其多晶粉末。利用其粉末X射线衍射数据,采用直接空间搜索法解析其晶体结构,结果表明:该晶体属单斜晶系,P21空间群,晶胞参数a=1.253 9 nm,b=0.737 1nm,c=1.229 6 nm,α=γ=90°,β=106.192°,Z=2,V=113.649 7 nm3。After extracted from Voacanga africana Staph.,the crude sample was purified and recrystallized to get polycrystalline powder.The crystal structure of Hydrochloride Tabersonine was determined from its X-ray powder diffraction pattern through calculational crystallography methods.The results showed that the the caystal structure of hydrochloride tabersonine is monoclinic,space group P21 with unit cell dimensions a=1.253 9 nm,b=0.737 1 nm,c=1.229 6 nm,α=γ=90°,β=106.192°,Z =2,V=113.649 7 nm3.

关 键 词：盐酸柳叶水甘草碱 X射线粉末衍射 晶体结构 

分 类 号：O76[理学—晶体学]