Facile Synthesis of Phosphorus N-Fluoroalkanesulfonyl Amidines by Cu-catalyzed One-pot Three-component Reaction  

作　　者：张振华 熊婉婷 顾继伟 朱士正 

机构地区：[1]Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China

出　　处：《Chinese Journal of Chemistry》2011年第12期2675-2680,共6页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （Nos. 21032006, 20972178） and Shanghai Natural Science Council.

摘　　要：In the presence of Cu（I） and triethyl amine, one-pot three-component reaction of fluoroalkanesulfonyl azides, alkynes and iminophosphoranes in CH2Cl2 at room temperature gave a novel class of fluorinated phosphorus amidines in good yields.In the presence of Cu（I） and triethyl amine, one-pot three-component reaction of fluoroalkanesulfonyl azides, alkynes and iminophosphoranes in CH2Cl2 at room temperature gave a novel class of fluorinated phosphorus amidines in good yields.

关 键 词：fluoroalkanesulfonyl azide IMINOPHOSPHORANE ALKYNE three-component reaction AMIDINE 

分 类 号：TQ463.25[化学工程—制药化工] TQ638