On the Absolute Configuration of Schweinfurthinol  

作　　者：崔杉 伍贻康 高坡 

机构地区：[1]School of Chemistry and Materials, Heilongjiang University, Harbin, Heilongjiang 150080, China [2]State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

出　　处：《Chinese Journal of Chemistry》2011年第12期2759-2762,共4页中国化学（英文版）

基　　金：Project supported by the National Basic Research Program of China （973 Program） （No. 2010CB833200）, the National Natural Science Foundation of China （Nos. 21172247, 21032002, 20921091, 20672129, 20621062, 20772143） and the Chinese Academy of Sciences （＂Knowledge Innovation＂, KJCX2.YW.H08）.

摘　　要：Through the chiral-pool based synthesis of both enantiomers of schweinfurthinol, it has been proven that this natural product isolated from the seeds of Canarium schweinfurthii possesses an （S） configuration. The optical rotation data for pure schweinfurthinol is also updated.Through the chiral-pool based synthesis of both enantiomers of schweinfurthinol, it has been proven that this natural product isolated from the seeds of Canarium schweinfurthii possesses an （S） configuration. The optical rotation data for pure schweinfurthinol is also updated.

关 键 词：natural products chiral building blocks DIOLS PHENOLS CARBANIONS 

分 类 号：TQ658[化学工程—精细化工] O629.711[理学—有机化学]