Glass-ceramics made from arc-melting slag of waste incineration fly ash  

作　　者：刘汉桥 魏国侠 梁茵 董飞英 

机构地区：[1]Department of Energy and Mechanics Engineering, Tianjin Institute of Urban Construction

出　　处：《Journal of Central South University》2011年第6期1945-1952,共8页中南大学学报（英文版）

基　　金：Project(20806051) supported by the National Natural Science Foundation of China;Project(20080440680) supported by China Postdoctoral Science Foundation

摘　　要：Grate fly ash and fluidized bed fly ash mixed with glass cullet additive respectively were melted in the electronic arc-furnace. The product, arc-melting slag, was further treated by crushing, pressing and heat treatment in order to make the glass-ceramics. The crystallization behaviors of the produced glass-ceramics were examined by differential thermal analysis （DTA）, X-ray diffractometry （XRD） and scanning electron microscopy （SEM）. Results show that main crystalline phase of the glass-ceramics fi＇om grate fly ash is wollastonite （CaSiO3） with small amount of diopside （Ca（Mg,Al）（Si,Al）206）, and that from fluidized bed fly ash is diopside （Ca（Mg,Al）（Si,Al）206）. It is found that the glass-ceramics sintered at 850 ℃and 1 000℃ from grate fly ash and fluidized bed fly ash respectively have the optimal physical, mechanical and chemical characteristics. Glass-ceramics samples, produced from incinerator fly ash with desirable properties and the low leaching concentration of heavy metals, can be the substitute of nature materials such as marble, granite and porcelain tiles.Grate fly ash and fluidized bed fly ash mixed with glass cullet additive respectively were melted in the electronic arc-furnace. The product, arc-melting slag, was further treated by crushing, pressing and heat treatment in order to make the glass-ceramics. The crystallization behaviors of the produced glass-ceramics were examined by differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). Results show that main crystalline phase of the glass-ceramics from grate fly ash is wollastonite (CaSiO3) with small amount of diopside (Ca(Mg,Al)(Si,Al)2O6), and that from fluidized bed fly ash is diopside (Ca(Mg,Al)(Si,Al)2O6). It is found that the glass-ceramics sintered at 850 °C and 1 000 °C from grate fly ash and fluidized bed fly ash respectively have the optimal physical, mechanical and chemical characteristics. Glass-ceramics samples, produced from incinerator fly ash with desirable properties and the low leaching concentration of heavy metals, can be the substitute of nature materials such as marble, granite and porcelain tiles.

关 键 词：waste incineration fly ash ARC-MELTING GLASS-CERAMICS crystallization behavior 

分 类 号：TQ174.1[化学工程—陶瓷工业]