多环麝香中间体六甲基茚满的催化合成  

Catalytic Synthesis of Hexamethyl Indane-Intermediate of Polycyclic Musk

作　　者：白杨[1] 周调调[1] 宋先亮[1] 刘六军[1] 

机构地区：[1]北京林业大学,北京100083

出　　处：《东北林业大学学报》2011年第12期104-106,共3页Journal of Northeast Forestry University

基　　金：林业科技成果推广计划(200819);国家"973"计划项目(973-2010CB732204)

摘　　要：以对伞花烃为原料,叔戊醇作烷基化试剂,对合成多环麝香中间体1,1,2,3,3,5-六甲基茚满反应的催化剂种类及影响因素进行对比研究。结果表明:以自制Fe2(SO4)3/AlCl3固体超强酸为催化剂,用量为10%,对伞花烃与叔戊醇的摩尔比为2.0∶1.0,反应温度为8℃,滴加反应时间为2.5 h,六甲基茚满的产率最高,为15.88%。The types of catalysts and influencing factors were studied in the synthesis of 1,1,2,3,3,5-hexamethyI indane, using p-cymene as raw material and tert-amyl alcohol as alkylation reagent. The maximum yield of 1,1,2,3,3,5-hexamethylindane （15.88%） were obtained as the dosage of the self-made Fe2（ SO4 ）3/AlCl3 solid superaeid catalyst 10%, the molar ratio of p-eymene to tert-amyl alcohol 2.0 ： 1.0, reaction temperature 8 degrees C, and the reaction time 2.5 h.

关 键 词：对伞花烃 1 1 2 3 3 5-六甲基茚满 麝香 催化合成 

分 类 号：TQ651.1[化学工程—精细化工]