钴催化剂催化高碳烯烃氢甲酰化反应的研究进展  

Development on Cobalt-Catalyzed Hydroformylation of Higher Olefins

作　　者：吴丹[1] 张建伟[1] 蒋景阳[1] 

机构地区：[1]大连理工大学化工与环境生命学部精细化工国家重点实验室,辽宁大连116012

出　　处：《石油化工》2011年第12期1370-1374,共5页Petrochemical Technology

基　　金：教育部博士点基金项目(20070141046);辽宁省教育厅优秀人才支持计划项目(辽教发[2006]124号)

摘　　要：针对均相钴催化剂催化高碳烯烃氢甲酰化反应的工业生产工艺,介绍了关于羰基氢钴催化剂制备方法的改进、用于改性钴催化剂的膦配体以及工业上现有的钴催化剂回收途径,并综述了液液两相体系中钴催化剂催化高碳烯烃氢甲酰化反应的研究进展。在水-有机两相体系中进行的钴催化剂催化氢甲酰化反应,可在保持催化剂较高活性和选择性的基础上实现催化剂的简易分离回收与循环使用,因此开发性能优越的水-有机两相催化体系是该领域的研究方向。In view of the industrial homogeneous cobalt-catalyzed hydroformylation of higher olefins,the innovation of the formation of cobalt hydrotetracarbonyl catalyst and phosphine ligands for the modification of the cobalt catalysts,the present industrial methods for the recovery of cobalt and the development of cobalt-catalyzed higher olefins hydroformylation in the liquid/liquid biphasic system were summarized in this review.Cobalt-catalyzed hydroformylation in aqueous/organic biphase system makes the easy catalyst recycling as well as maintaining the catalyst activity and selectivity,so exploration of excellent aqueous/organic biphase catalytic system is still an important topic of R D in the future.

关 键 词：高碳烯烃 氢甲酰化 钴催化剂 液液两相催化 

分 类 号：TQ223.1[化学工程—有机化工]