Gated container molecules  

作　　者：HOUK K.N. 

机构地区：[1]Department of Chemistry and Biochemistry,University of California at Los Angeles,Los Angeles

出　　处：《Science China Chemistry》2011年第12期2038-2044,共7页中国科学（化学英文版）

基　　金：the National Institute of General Medical Sciences,National Institutes of Health;the National Science Foundation for financial support of the research;the Cross-disciplinary Scholars in Science and Technology program of UCLA for support to F.L

摘　　要：Donald J. Cram, the great UCLA chemist, received the Nobel Prize for his discoveries about host-guest complexes . Both theoretical and experimental studies have been conducted about the nature and strength of interactions between the host and guest molecules. The concepts of constrictive binding （the activation energy of the binding process） and intrinsic binding （the free energy difference between the complex and the free host and guest molecules） were introduced to characterize different binding properties （Figure 1）Donald J. Cram, the great UCLA chemist, received the No-bel Prize for his discoveries about host-guest complexes [1]. Both theoretical and experimental studies have been con-ducted about the

关 键 词：客体分子 容器 闸门 主客体配合物 加州大学 诺贝尔奖 相互作用 结合特性 

分 类 号：O641.1[理学—物理化学]