水性聚氨酯/氧化石墨烯复合材料的研究  

Research on Water-based Polyurethane/Graphene Oxide Composite Material

作　　者：王乾乾[1] 王全杰[1,2] 

机构地区：[1]烟台大学化学化工学院,山东烟台264005 [2]国家制革技术研究与推广中心,山东烟台264003

出　　处：《西部皮革》2011年第24期26-29,34,共5页West Leather

基　　金：山东省科技攻关项目(2008GG10003020)

摘　　要：采用改进的Hummers法制备氧化石墨(GO),超声剥离得到氧化石墨烯(GOs)。采用TEM、FT-IR和XRD表征了形貌与结构,表明制备的GOs剥离比较完全,稳定性较好。将GOs与水性聚氨酯(WPU)共混,正交试验法研究结果表明:GOs的含量对WPU/GOs复合材料耐水性的影响最大,而共混温度对力学性能的影响最大。Graphite oxide（GO） was prepared by improved Hummers method, and then graphene oxide（GOs） was obtained via ultrasonic stripping. The morphology and structure of GOs were characterized by TEM, FT-IR and XRD. The results showed that the prepared almost completely tripped GOs had good stability. The waterborne polyurethane/grapheme oxide composite material was obtained by blending GOs with water-based polyurethane, and the results, obtained by the orthogonal test method, showed that the dosage of GOs had the greatest effect on the water resistance, but the blended temperature was the main factor on mechanical properties.

关 键 词：氧化石墨烯 水性聚氨酯 改性 正交试验法 

分 类 号：TB383-1[一般工业技术—材料科学与工程]