HIPS/OMMT纳米复合材料燃烧炭渣结构分析  

Analysis on Burning Char Residue of HIPS/OMMT Nanocomposite

作　　者：白卯娟[1] 张军[1] 

机构地区：[1]青岛科技大学环境与安全工程学院,山东青岛266042

出　　处：《现代塑料加工应用》2011年第6期10-13,共4页Modern Plastics Processing and Applications

基　　金：国家自然科学基金资助项目(50876048);青岛市科技计划基础研究项目(09-1-3-26-jch)

摘　　要：采用扫描电子显微镜(SEM)及热重分析(TGA)方法对高抗冲聚苯乙烯(HIPS)/有机蒙脱土(OMMT)纳米复合材料在锥形量热仪试验中不同燃烧时间段形成炭渣的结构、热稳定性和热分解特性进行了分析研究。结果表明,复合材料在热释放速率为峰值时开始形成皮层-窝层组合的炭层结构,皮层中形成少量热稳定性较好的碳质物,提高了皮层的热稳定性,燃烧结束时碳质物被氧化,留下蒙脱土(MMT)片层;窝层热稳定性较差,但增大了炭层的体积;皮层和窝层的组合对复合材料起到阻燃作用,其中皮层起主要作用。The structure characteristics, the thermal stability and pyrolysis characteristics of the char residue of HIPS/OMMT nanocomposite in different stages of burning process in cone calorimeter were studied by SEM and TG. The experimental results show that the skin-cellular layer come into being at peak HRR stage and a few carbonaceous matter form during burning, thereby the thermal stability of skin layer is improved. The carbonaceous matter is oxidized and montmorillonite plates is left. The thermal stability of the cellular char layer is not as good as that of the skin char layer, but the cellular char layer augments the bulk of char layer. It is the perfect combina- tion of the skin and cellular layers that imparts flame retardancy to the nanocomposite, and the skin layer plays a critical part.

关 键 词：高抗冲聚苯乙烯 纳米复合材料 阻燃 聚合物层状硅酸盐 炭层结构 热稳定性 

分 类 号：TB383.1[一般工业技术—材料科学与工程]