V_2O_5/ACO催化过氧化氢氧化苯乙烯的研究  

Study on the Oxidation of Styrene with Hydrogen Peroxide Catalyzed by V_2O_5/ACO

作　　者：肖毅[1,2] 黄红梅[1] 尹笃林[1,2] 毛丽秋[1,2] 伏再辉[1,2] 

机构地区：[1]化学生物学及中药分析教育部重点实验室,中国长沙410081 [2]湖南师范大学精细催化合成研究所,中国长沙410081

出　　处：《湖南师范大学自然科学学报》2011年第6期58-61,共4页Journal of Natural Science of Hunan Normal University

基　　金：国家自然科学基金资助项目(20572021;20805014);湖南省自然科学基金资助项目(09JJ3018);湖南省教育厅科学研究基金资助项目(11C0809)

摘　　要：以氧化改性活性炭为载体,用微波辐射法制备了系列钒氧化物/活性炭催化剂(V2O5/ACO).采用FT-IR、XRD对催化剂进行了光谱表征.考察了V2O5/ACO在苯乙烯过氧化氢选择氧化中的催化性能.其中,V2O5-30/ACO性能较佳.以丙酮为反应介质,当n(苯乙烯)∶n(H2O2)=1∶2.5,45℃反应5 h,苯乙烯转化完全,苯甲醛的选择性可达87.2%.V2O5-30/ACO经纯化后可再生,其催化性能基本保持不变.A series of activated carbon-supported vanadium oxide catalysts （V20s/ACO） were prepared from oxygenated activated carbon （ACO） by microwave irradiation. The obtained catalysts were characterized by FT-IR and XRD. The catalytsis effect of V2O5/ACO on the selective oxidation of styrene with hydrogen peroxide was investigated. Among them, V2O5-30/ACO presented better performance. Complete conversion of styrene and 87.2% selectivity for benzaldehyde were achieved in acetone under the conditions of styrene： H2O2 = 1：2.5 （mol/mol）, 45℃ and 5 h. V2O5/ACO catalyst could be regenerated to maintain its eatalytsis performance after purification.

关 键 词：V2O5/活性炭 过氧化氢 催化氧化 苯乙烯 苯甲醛 

分 类 号：TQ032[化学工程]