α-烯基聚醚衍生物在地层介质中的吸附与矿化度的相关性  

Relationship Between Adsorption of α-olefine Polyether Derivative and Salinity in Geological Media

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作  者:王晓东[1] 谢瑞瑞[1] 辛寅昌[1] 赵明方 

机构地区:[1]山东师范大学化学化工与材料科学学院,山东济南250014 [2]中国石油西北钻探局,新疆乌鲁木齐830000

出  处:《石油学报(石油加工)》2011年第6期994-998,共5页Acta Petrolei Sinica(Petroleum Processing Section)

基  金:国家科技部创新基金(01C26213700899)资助

摘  要:α-烯基聚醚衍生物具有很高的耐盐性,已经用于高矿化度稠油的乳化降黏。研究了α-烯基聚醚衍生物在地层介质包括蒙脱土、碳酸盐和硅酸盐中的吸附性,并阐述了α-烯基聚醚衍生物抗地层吸附的原理。结果表明,α-烯基聚醚衍生物与一般常用表面活性剂相比,在使高矿化度水具有低表面张力的同时,在地层介质中的吸附量也随着矿化度的增加而减少。由于α-烯基聚醚衍生物具有很高的耐盐能力,可与KCl复合使用,能有效地抑制地层膨胀,减少地层介质的吸附。With the character of high salt-resistance,α-olefine polyether derivative had been used in emulsification and viscosity-decreasing of high-salinity heavy oil.Its adsorption in different geological media including montmorillonite,carbonate and silicate was studied.The mechanism of α-olefine polyether derivative's resisting stratigraphic medium's adsorption was elaborated also.Under the same condition,it is discovered that,compared to common surfactant,α-olefine polyether derivative can lead high-salinity solution to have low surface tension,meanwhile,its adsorption in geological media decreased obviously with the increase of the solution salinity.Because of high salt-resistance,α-olefine polyether derivatives can effectively inhibit the bulge of geological medium and decrease the absorption on geological medium,while combining with KCl.

关 键 词:α-烯基聚醚衍生物 紫外可见分光光度法 吸附 抑制膨胀 

分 类 号:TQ423[化学工程]

 

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