树状碳水化合物Ⅱ——液晶性的研究  

Dendronized Carbohydrates Ⅱ——Liquid Crystallinity Study

作　　者：杨柳林[1,2] 董炎明[2] 胡晓兰[2] 刘安华[2] 

机构地区：[1]厦门大学化学化工学院,厦门361005 [2]厦门大学材料学院,厦门361005

出　　处：《化学学报》2012年第1期27-34,共8页Acta Chimica Sinica

基　　金：国家自然科学基金(No.20774077)资助项目~~

摘　　要：以基于单糖为内核,楔形液晶基元DOBOB酸(3,4,5-三[对-(十二烷氧基)苄氧基]苯甲酸)为分枝的树状碳水化合物液晶为研究对象,利用DSC、热台偏光显微镜、XRD和CD/UV光谱等手段研究该类化合物的液晶性.研究发现分枝的数目对该类化合物的液晶性有显著影响,以2-乙酰氨基葡萄糖为内核的包含四个分枝的树状分子具有最高的液晶结构有序性,清亮点也显著高于另两种单糖内核(含五个分枝)的树状分子.此外,该类碳水化合物液晶形成的液晶相都具备超分子手性,为探索碳水化合物手性液晶相提供了一条新的思路.Liquid crystallinity of dendronized carbohydrate liquid crystals,which contain carbohydrate core and mesogen branches DOBOB（3,4,5-tris（p-dodecyloxybenzyloxy） benzoic acid）,was studied by DSC,thermal polarized optical microscopy,XRD and CD/UV spectrum.The number of branches affects the liq-uid crystallinity significantly.Dendrimer that contains four branches has the highest liquid crystal structure order,and the clearing point is also higher than the other two dendrimers which contain five branches.Oth-erwise,supramolecular chirality is also expressed in the mesophase formed by these dendronized carbohy-drates,which may provide inspiration in searching for chiral mesophase of carbohydrate liquid crystals.

关 键 词：树状碳水化合物液晶 3 4 5-三[对-(十二烷氧基)苄氧基]苯甲酸 手性液晶相 

分 类 号：O753.2[理学—晶体学]