热孔计法表征水泥基材料孔结构的热力学计算模型  

Thermodynamic Calculational Model for Pore Structure Characterization of Cement-Based Material by Thermoporometry

作　　者：蒋正武[1] 张楠[1] 杨正宏[1] 

机构地区：[1]同济大学,先进土木工程材料教育部重点实验室,上海200092

出　　处：《硅酸盐学报》2012年第2期194-199,共6页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金(51078269);国家重点基础研究发展计划(2011CB013800);国家科技支撑计划(2011BAE14B06);光华同济土木学院基金资助项目

摘　　要：提出了一种采用热孔计法表征水泥基材料的内部微孔结构及其分布的新方法。利用热力学、相变等基本理论,建立了热孔计法表征水泥基材料孔结构的热力学计算模型,并研究了该方法表征水泥基材料的各种孔结构特征参数。结果表明,所建立的热孔计法孔结构热力学计算模型可用于表征水泥基材料中微孔的孔型、孔隙率、孔径分布等的孔结构信息,其结果具有再现性。A method of thermoporometry （TPM） characterizing pore structure and pore distribution of cement-based material was proposed. The thermodynamic calculational model of pore structure characterization of cement-based material by TPM was estab- lished based on theormodynamics and phase change theories. The pore structure parameters of cement-based material were investi- gated by the TPM. The results indicate that the micropore information of cement-based materials such as pore shape, porosity and pore distribution can be characterized by the thermodynamic ealculational model.

关 键 词：热孔计法 孔结构 水泥基材料 热力学 计算模型 

分 类 号：TU528.2[建筑科学—建筑技术科学]