钯/铝双金属体系对3-氯酚的脱氯降解  

Dechlorination degradation of 3-chlorophenol with Pd/Al bimetallic system

作　　者：杨波[1,2] 邓述波[2] 余刚[2] 赵绪新[1] 刘剑洪[1] 

机构地区：[1]深圳大学化学与化工学院,深圳518060 [2]清华大学环境学院持久性有机污染物研究中心,北京100084

出　　处：《环境工程学报》2012年第2期381-384,共4页Chinese Journal of Environmental Engineering

基　　金：国家高技术研究发展计划(863)项目(2009AA063902);北京市优秀博士学位论文指导教师科技项目(YB20081000304);环境模拟与污染控制国家重点联合实验室专项经费(09K03ESPCT);深圳大学科研基金资助面上项目(200909)

摘　　要：研究了钯/铝双金属体系对水相中3-氯酚的催化脱氯降解效果,通过置换沉积制备了钯/铝双金属颗粒,考察了该双金属颗粒的稳定性以及溶液pH和钯负载量对脱氯效果的影响。结果表明,pH在4.0以下的酸性条件,钯负载量在1.43%时,可实现水相中3-氯酚的有效脱氯,反应30 min后0.389 mmol/L的3-氯酚转化率可达99%以上,产物主要为苯酚,而钯/铝颗粒在重复测试中能保持较好的稳定性,这与铝基材表面自发形成的氧化膜有关。钯/铝材料表征的结果表明,钯颗粒高度分散在铝基材表面,并极大地提高了铝基材的表面积,从而有助于后续的脱氯反应。The catalytic dechlorination of 3-chlorophenol（3-CP） in aqueous solution with Pd/Al bimetallic system was investigated.The Pd/Al bimetallic particles were prepared with the cementation method.The stability of dechlorination reactivity of Pd/Al was tested.The effects of the solution pH and the amount of Pd loading at Al particles on dechlorination performance were studied.The results indicated that 3-CP（0.389 mmol/L） could be rapidly dechlorinated into phenol by Pd/Al particles with 99% conversion rate during 30 min under the conditions of pH ≤ 4.0 and 1.43% Pd loading.During the repeated tests,Pd/Al particles maintained well stability for the dechlorination of 3-CP,which is related to the spontaneously formed oxide film on Al substrate.The characterizations of Pd/Al particles indicated that the tiny Pd islets were uniformly dispersed on Al particle surface and the surface area of Al particles greatly increased due to Pd loading.As a result,the high dechlorination performance was obtained in this work.

关 键 词：钯/铝双金属 3-氯酚 脱氯 酸性溶液 

分 类 号：X703.1[环境科学与工程—环境工程]