用烷基醇Gemini表面活性剂替代烷基酚聚氧乙烯醚合成苯丙乳液  

Syntheses of Styrene-acrylic Emulsion Using Alkylalcohol Gemini Surfactants to Replace Alkylphenolic Ethoxylates

作　　者：郑清皇[1] 张超[1] 陈燕红[1] 吴宗华[1] 

机构地区：[1]福建师范大学化学与材料学院,福建福州350108

出　　处：《福建师范大学学报（自然科学版）》2012年第1期77-81,共5页Journal of Fujian Normal University：Natural Science Edition

摘　　要：分别用琥珀酸聚乙二醇辛醇双酯磺酸钠(RCS-8),琥珀酸聚乙二醇十二正烷醇双酯磺酸钠(RCS-12)和琥珀酸壬基酚聚氧乙烯(10)醚酯磺酸钠(RCD-NP)为乳化剂合成了苯丙乳液,并进行了乳液表面张力、机械稳定性、粒径和粒径分布等的测试和比较.结果表明,烷基醇Gemini表面活性剂可以取代烷基酚聚氧乙烯醚用于苯丙乳液合成,其结构对合成乳液的性能影响大.采用RCS-8与RCD-NP为乳化剂合成的苯丙乳液其主要理化性能无明显差异,而其凝胶率、机械稳定性、粒径分布等方面优于后者.聚合温度为80℃,引发剂用量为单体质量的1%时,用RCS-8合成的苯丙乳液的粒径最小,粒径分布范围最窄.The syntheses of styrene-acrylic emulsion was carried out,using the following three emulsifiers：the sodium polyethylene-glycol octyl alcohol sufisuccinates（RCS-8）,the sodium polyethylene-glycol lauryl alcohol sufisuccinates（RCS-12） and the sodium succinate nonylphenol ethoxylate（RCD-NP） respectively.Their surface tension,mechanical stability,partical size and particle size distributions were determined and compared to others.The results showed that the syntheses of styrene-acrylic emulsion could be used the alkyl-alcohol Gemini surfactants to replace the alkyl-phenol ethoxylates,the structures of emulsifiers had a big effect on the syntheses.The main physicochemical properties of the styrene-acrylic emulsion synthesized by the emulsifiers of RCS-8 and RCD-NP had no obvious difference,but the gel-rate,mechanical stability,and particle size distributions were better than the latter.When the temperature of polymerization was 80 ℃,the amount of initiator was 1% of monomer contents,the partical size of styrene-acrylic emulsion which was synthesized by RCS-8 was the smallest,the partical size distribution was the narrowest.

关 键 词：苯丙乳液 GEMINI表面活性剂 替代 烷基酚聚氧乙烯醚 

分 类 号：TQ423[化学工程]