邻甲硼酚醛树脂固化双酚-A环氧树脂及其复合材料的性能  

Properties of boron-containing o-cresol-formaldehyde resin cured BPAER and its fiberglass-reinforced composite

作　　者：林浩杰[1] 高俊刚[1] 刘丰[1] 吴小晶[1] 

机构地区：[1]河北大学化学与环境科学学院,河北省保定市071002

出　　处：《合成树脂及塑料》2012年第1期61-64,共4页China Synthetic Resin and Plastics

基　　金：河北省自然科学基金资助项目(E2010000287)

摘　　要：用邻甲硼酚醛树脂(BoPFR)固化双酚-A环氧树脂(BPAER),制备了含硼酚醛的高性能玻璃钢复合材料。分析了固化过程,研究了固化树脂以及玻璃纤维层压板的力学性能、热性能和电性能。当m(BoPFR)/m(BPAER)为1.0∶0.5时,复合材料的玻璃化转变温度从198.4℃下降到134.5℃,材料韧性提高。固化物有良好的耐热性能,当m(BoPFR)/m(BPAER)为1.0∶0.2时,材料在900℃时的残留率为25.83%,热降解动力学符合一级反应动力学;玻璃纤维层压板拉伸强度提高了一倍,而电性能变化不大。High-performance fiberglass-reinforced composites comprising boron-containing o-cresol formaldehyde resin（BoPFR） were prepared via curing bisphenol-A epoxy resin（BPAER） with BoPFR.The curing process was analyzed.The mechanical,thermal and electrical properties of the cured resin and its fiberglass-reinforced laminate were studied.When the mass ratio of BoPFR to BPAER was 1.0 ∶ 0.5,the glass transition temperature of the composites lowered from 198.4 ℃ to 134.5 ℃ and thereby the toughness of the composites increased.The cured resin had good thermal property.The residual rate of the cured sample at 900 ℃ was 25.83% when the mass ratio of BoPFR to BPAER was 1.0 ∶ 0.2.The thermal degradation kinetics accorded with first-order reaction.The fiberglass-reinforced laminate′s tensile strength increased by 100% and whereas its electrical properties changed little.

关 键 词：邻甲硼酚醛树脂 双酚-A 环氧树脂 热性能 玻璃钢 力学性能 

分 类 号：TQ323.5[化学工程—合成树脂塑料工业]