新型水溶性超支化聚酰胺-酯的合成  

Synthesis of a Novel Water-solubility Hyperbranched Poly(amido-ester)

作　　者：梁志彬[1] 赵殊[1] 王兴宁[1] 郭超[1] 吴宁[1] 王婧[1] 

机构地区：[1]东北林业大学理学院黑龙江省阻燃材料分子设计与制备重点实验室,黑龙江哈尔滨150040

出　　处：《合成化学》2012年第1期32-35,共4页Chinese Journal of Synthetic Chemistry

基　　金：国家科技支撑计划资助项目(2006BAE03B06)

摘　　要：均苯四甲酸酐与二乙醇胺经酰化反应制得中心核(4);4与AB2单体2,2-二羟甲基丙酸经熔融缩聚合成了一种新型水溶性的二代超支化聚酰胺-酯(1),其结构与性能经FT-IR,GPC,粘度法,化学滴定等表征。4的Mn=1 683,Mw=1 911,Mw/Mn=1.14,[ηinh]=0.067 6 dL·g-1;1的Mn=3 750,Mw=4 904,Mw/Mn=1.31,[ηinh]=0.086 1 dL·g-1。A novel water-solubility the second generation of hyperbranched poly（amido-ester）（1） was synthesized by melt polycondensation of dimethylolpropionic acid as AB2 monomer and 4 as central core which was prepared by acylation reaction of pyromellitic dianhydride and diethanol amine.The structures were characterized by IR,GPC,chemical titration and viscosity measurement.Mn,Mw and Mw/Mn of 4 were 1 683,1 911 and 1.14,and these of 1 were 3 750,4 904 and 1.31,respectively. of 4 and 1 were 0.067 6 dL·g-1 and 0.086 1 dL·g-1,respectively.

关 键 词：超支化 聚酰胺-酯 均苯四甲酸酐 合成 

分 类 号：O633.22[理学—高分子化学]