二茂铁双酰腙化合物的合成及电化学性质  

Synthesis and electrochemical properties of ferrocenyl hydrazone compounds

作　　者：李世俊[1] 朱登勇[1] 冉春玲[1] 李文娟[1] 徐琰[1] 唐明生[1] 樊耀亭[1] 

机构地区：[1]郑州大学化学系,河南郑州450001

出　　处：《化学研究与应用》2012年第2期187-191,共5页Chemical Research and Application

基　　金：国家自然科学基金项目(21171149)资助

摘　　要：以二茂铁双酰肼为原料,合成出两个二茂铁基酰腙类物质,通过元素分析、IR、1H NMR等分析手段确定了化合物的组成;电化学研究表明,化合物a在高电位区有两个不可逆氧化峰,应是酰腙活性基团被氧化的结果,通过量化计算,得到了化合物a的稳定结构。Two ferrocenyl hydrazone compounds were synthesized by 1, l＇-ferrocenyl diacylformylhydrazine with nitrabenzalde- hyde. The compounds were characterized by elemental analysis, IR, and ^1 H NMR spectrum. The electrochemical studies indicated that compound a showed two inreversible oxidation peaks in the high potential. It should be the result of the oxidation of the activity hydrazone group. The stable configuration of compound a was obtained by the quantitative calculation.

关 键 词：二茂铁酰腙 合成 电化学 量化计算 

分 类 号：O627[理学—有机化学]