原子荧光法检验小白菜中砷制样均匀性不确定度的评定  

Evaluation on the Uncertainty of Samples Homogeneity in Detecting as in Pakchoi by Atomic Fluorescence Method

作　　者：占永革[1] 龚剑[1] 黄湘燕 陈飒 李志梅 王伟彤[1] 

机构地区：[1]广州大学环境检测中心 [2]中山市供水有限公司水质检测中心,广东中山528403

出　　处：《食品与发酵工业》2011年第12期137-140,共4页Food and Fermentation Industries

基　　金：国家自然科学基金资助项目(40903040)

摘　　要：为探索食品检验制样均匀性对检测结果分散性的影响,以原子荧光法检测小白菜中砷为例,采集了一组四分取样过程中取舍的样品并测得其数据,用单因素方差分析法检验出样品间的均匀性存在差异,算得其相对不确定度为10-2量级,此量级与常占主要地位的曲线拟合浓度的不确定度、回收率及方法偏差不确定度的量级相当。表明制样均匀性不确定度是非均匀性食品样品测量不确定度的主要来源之一,在评估非均匀性食品样品测量不确定度时不可忽视制样环节均匀性的影响。To explore the influence of homogeneity in sample preparation on the test dispersion,As detecting in pakchoi by atomic fluorescence method was studied.Data from a group of samples reserved or deleted by the process of quartering method.The differences of homogeneity between the samples were analyzed by the one-factor variable method.The result of uncertainty magnitude was of 10-2.The relative uncertainty of the differences is the same as the uncertainty of dominant concentration curve,percentage of recovery and method bias uncertainty.Hence,the results show that,the uncertainty of homogeneity sample mainly generates the measurement uncertainty of heterogeneity food samples.The influence of homogeneity coming from sample preparation cannot be ignored in the evaluating of uncertainty of heterogeneity food samples.

关 键 词：原子荧光法 制样 蔬菜 均匀性 砷 不确定度 

分 类 号：TS255.7[轻工技术与工程—农产品加工及贮藏工程] O657.31[轻工技术与工程—食品科学与工程]