阔叶树皮木醋液与木焦油有机成分的气相色谱分析  

Comparative Study on Capillary Gas Chromatographic Analysis of Organic Components of Wood Vineger and Water-Extract of Wood-Tar Prepared from Hard Wood Barks

作　　者：李元祥[1,2] 林红卫[2] 

机构地区：[1]怀化学院民族药用植物资源研究与利用湖南省重点实验室,湖南怀化418008 [2]怀化学院化学与化学工程系,湖南怀化418008

出　　处：《分析科学学报》2012年第1期58-62,共5页Journal of Analytical Science

基　　金：湖南师范大学生物学及中药分析教育部重点实验室开放基金(No.KLCBTCMR2008-05);怀化学院民族药用植物资源研究与利用湖南省重点实验室资助项目(No.SYSXM200911)

摘　　要：运用气相色谱对阔叶树皮木醋液及木焦油水提取液的有机成分,如醇类、羧酸类、酮类、酚类等进行了定量分析。结果表明,木醋液随着蒸馏处理,甲醇、乙醇、丙酮等低沸点物质主要分布在前馏液中,2,6-二甲氧基苯酚、甲基环戊烯醇酮、2-甲基-3-羟基-4-吡喃酮等高沸点物质主要分布在残馏液中。通过阔叶树皮木醋液及木焦油水提取液的两种主馏分所含有机成分的定量分析比较,表明除甲醇、乙酸、丙酸、2-呋喃醛等成分以外,二者具有相似的化学成分组成。The wood vineger and the water-extracted solution of wood-tar prepared from hard wood barks were analyzed by capillary gas chromatography.Thirty-seven compounds such as alcohols,carboxylic acids,ketones and phenols were determined.The low boiling poirtcompounds such as methanol,ethanol,acetone etc.mainly exist in the frant cut fraction and the high boiling point compounds such as syringol,cyclotene,maltol etc.mainly exist in the distillate residue.The constituent varieties and contents of the water-extracted solution of the wood-tar were found to be similar to those of the wood vinegar except methanol,acetic acid,propionic acid,furfural by comparative analysis.

关 键 词：木醋液 木焦油 水提取液 阔叶树皮 气相色谱 

分 类 号：O657.71[理学—分析化学]