阴离子双子表面活性剂驱油性能研究  

Performance of Anionic Gemini Surfactant in Enhancement of Oil Recovery

作　　者：胡小冬[1] 唐善法[1,2] 刘勇[3] 文守成[1,2] 闫双喜[1] 

机构地区：[1]长江大学石油工程学院,湖北荆州434023 [2]中国石油采油采气重点实验室长江大学研究室,湖北荆州434023 [3]长庆油田分公司第三采油技术服务处,宁夏银川750006

出　　处：《油田化学》2012年第1期57-59,79,共4页Oilfield Chemistry

基　　金：中国石油天然气集团公司石油科技中青年创新基金项目"四次采油驱油剂的分子结构设计;合成与性能研究"(项目编号2002F70116)

摘　　要：对比了硫酸酯双子表面活性剂GA12-4-12与十二烷基硫酸钠的油水动态界面张力及驱油效果,研究了GA12-4-12与非离子表面活性剂ANT1、ANT2复配体系在不同渗透率和不同矿化度条件下的驱油性能。结果表明,GA12-4-12具有优于单链表面活性剂的界面活性和提高采收率能力,使用浓度仅为800 mg/L时,在水驱(65.38%)基础上提高采收率11.67%。GA12-4-12能适用于中、低渗油藏,其提高采收率的能力随着矿化度的增加而逐渐下降。复合驱替实验表明,在2.5×105mg/L矿化度条件下,在水驱(60%)基础上,SP体系(400 mg/LGA12-4-12+100 mg/L ANT1)使渗透率为48.3×10-3μm2的低渗透率岩心提高采收率10.67%;在5×104mg/L矿化度条件下,在水驱(57.89%)基础上SP体系(400 mg/L GA12-4-12+100 mg/L ANT2)使渗透率为417×10-3μm2的中低渗透率岩心能提高采收率8.42%。The dynamic interfacial tension of oil-water and the displacement effect of anion Gemini surfactants GA12-4-12 and dodecyl sulfate sodium were contrasted, and the displacement effect of the compound of GA12-4-12 and non-ionic suffactant ANT1, ANT2 was investigated in different permeability and salinity condition. The results showed that GA12-4-12 possessed superior inteffacial activity and ability to enhance the oil recovery, especially when the concentration of CA12-4-12 was 800 rag/L, the enhancement of oil recovery was 11.67% based on 63.38% of water flooding. GA12-4-12 was suitable for medium and low permeability reservoirs, however, the ability to enhance the oil recovery gradually declined with increasing salinity. Compound oil displacement experiments showed that in 2.5 × 105 mg/L salinity conditions, the oil recovery of low permeability cores of 48.3 ×10^-3μm^2was enhanced by the SP1 system （400 mg/L GA12-4-12 ＋ 100 mg/L ANT1） for 10.67% based on 60% of water flooding; in 5× 104 mg/L salinity conditions, the oil recovery of middle-low permeability cores of 417 ×10^-3μm^2 was enhanced by the SP2 system （400 mg/L GA12-4- 12 ＋ 100 mg/L ANT2） for 8. 42% based on 57.89% of water flooding.

关 键 词：阴离子双子表面活性剂 油水动态界面张力 复合驱油体系 高矿化度 

分 类 号：TE357.46[石油与天然气工程—油气田开发工程] TE39