Comparison of Photochemical Reactions of m-Cresol in Aqueous Solution and in Ice  

作　　者：PENG Fei1, XUE Hong-hai1, TANG Xiao-jian1,2, KANG Chun-li1, LI Lin-lin1 and LI Zhe1 1. Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun 130021, P. R. China 2. School of Municipal and Environmental Engineering, Jilin Institute of Architecture and Civil Engineering, Changchun 130118, P. R. China 

出　　处：《Chemical Research in Chinese Universities》2012年第1期47-52,共6页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(Nos.20577014 and 41073063)

摘　　要：We compared the photochemical reaction of m-cresol containing ·OH precursors such as H2O2, NO2 and NO3 in aqueous solution with those in ice. The results show that the conversion rate of m-cresol in aqueous solution was higher than that in ice. H2O2, NO2 and NO3 all accelerated the photoconversion of m-cresol in both aqueous solution and ice. The photochemical reactions of m-cresol obeys the first order kinetics equation. According to the photoproducts identified by GC-MS, we proposed that hydroxylation and nitration reactions occurred in both aqueous solution and ice. Coupling reaction was common in ice, however, in aqueous solution it was found only in UV system. Our results suggest that the photochemical reactions of m-cresol were different in aqueous solution and in ice.We compared the photochemical reaction of m-cresol containing ·OH precursors such as H2O2, NO2 and NO3 in aqueous solution with those in ice. The results show that the conversion rate of m-cresol in aqueous solution was higher than that in ice. H2O2, NO2 and NO3 all accelerated the photoconversion of m-cresol in both aqueous solution and ice. The photochemical reactions of m-cresol obeys the first order kinetics equation. According to the photoproducts identified by GC-MS, we proposed that hydroxylation and nitration reactions occurred in both aqueous solution and ice. Coupling reaction was common in ice, however, in aqueous solution it was found only in UV system. Our results suggest that the photochemical reactions of m-cresol were different in aqueous solution and in ice.

关 键 词：M-CRESOL PHOTOCHEMISTRY Aqueous solution ICE MECHANISM 

分 类 号：O621.2[理学—有机化学]