RuCl_3·3H_2O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations  

作　　者：SHAO Ming-bo1, LIU Gui-yan2, ZHAO Jing-jing1, WANG Xiao-yu1 and WANG Jian-hui1 1. Department of Chemistry, College of Science, Tianjin University, Tianjin 300072, P. R. China 2. Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China 

出　　处：《Chemical Research in Chinese Universities》2012年第1期67-69,共3页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(Nos.21072149, 20872108)

摘　　要：Herein lies a convenient and highly efficient method of olefin isomerization in the presence of RuCl3？3H2O in ionic liquid（IL）. More importantly, RuCl3？3H2O is a robust and recyclable catalyst. Nine cycles of RuCl3？3H2O as the catalyst were performed for the isomerization reactions of the selected substrate in IL and MeOH.Herein lies a convenient and highly efficient method of olefin isomerization in the presence of RuCl3？3H2O in ionic liquid（IL）. More importantly, RuCl3？3H2O is a robust and recyclable catalyst. Nine cycles of RuCl3？3H2O as the catalyst were performed for the isomerization reactions of the selected substrate in IL and MeOH.

关 键 词：Ruthenium trichloride Ionic liquid Olefin isomerization 

分 类 号：O621.2[理学—有机化学]