过渡金属改性的MCM-41中孔沸石的制备及性能  

PREPARATION AND PERFORMANCE OF MCM 41 MESOPOROUS ZEOLITE MODIFIED BY TRANSITION METALS

作　　者：童广明[1] 常志向[1] 刘东香[1] 

机构地区：[1]抚顺石油化工研究院,辽宁抚顺113001

出　　处：《石油炼制与化工》2000年第1期24-28,共5页Petroleum Processing and Petrochemicals

摘　　要：合成了Ｆｅ、Ｎｉ、Ｚｒ等过渡金属改性的ＭＣＭ－４１ 型中孔沸石，用红外光谱、Ｘ射线衍射及电子能谱进行研究，结果表明Ｆｅ、Ｎｉ、Ｚｒ等原子均已进入分子筛骨架。透射电镜分析结果显示出三种分子筛中分别有六角排列和四方排列的均一孔道。同时，对改性沸石的反应性能和酸性进行了初步研究。The synthesis of MCM 41 mesoporous zeolite modified by transition metals such as Fe, Ni and Zr is presented. The characterization of IR, XRD, XPS showed that the Fe, Ni and Zr atoms were entered the framework of the zeolite. The analysis of transmission electron micrographs illustrated that the modified zeolites possessed uniform channels with tetragonal or hexagonal arrangements. The catalytic properties and acidity of the modified zeolites were preliminary studied.

关 键 词：分子筛 制备 过渡金属 改性 沸石 催化剂 

分 类 号：TE624.99[石油与天然气工程—油气加工工程]