氮功能化大环化合物及其Ni(Ⅱ)配合物的合成和谱学研究  

Synthesis and Spectroscopic Studies of New N-functionalized Macrocyclic Compounds and Complex

作　　者：王世范[1] 谢复新[2] 倪诗圣[2] 

机构地区：[1]华东冶金学院化工系,马鞍山243002 [2]安徽大学化学系,合肥230039

出　　处：《光谱学与光谱分析》2000年第1期44-48,共5页Spectroscopy and Spectral Analysis

基　　金：国家自然科学基金资助

摘　　要：以丙酮、乙二胺、溴乙酸乙酯为原料合成了三种新的氮功能化四氮杂大环化合物和配合物 ,用元素分析、电子光谱、红外光谱。Three new N functionalized tetraazamacrocyclic compounds,C messo 5,5,7,12,12,14 hexamethyl 1,4,8,11 tetraazacyclotetradecane N,N′,N″,N tetrakis (ethyl acetate) (A),C messo 5,5,7,12,12,14 hexamethyl 1,4,8,11 tetra azacyclotetradecane N,N′,N″,N tetraacetic acid (H 4L) and the hydrobromide of H 4L have been synthesized and the complex Na 2[NiL]·2C 2H 5OH has been prepared as well.The macroyclic compounds and the complex have been studied by electronic spectrum,infrared spectrum, 1H NMR,MS and elemental analysis.

关 键 词：大环配体 氮杂大环化合物 镍配合物 

分 类 号：O626[理学—有机化学] O614.813[理学—化学]