N-烷基壳聚糖衍生物的合成及其对阳离子的吸附性能  被引量:16

Synthesis and Adsorption Properties of N-Alkyl Chitosans

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作  者:黄晓佳[1] 王爱勤[1] 袁光谱[1] 

机构地区:[1]中国科学院兰州化学物理研究所,兰州730000

出  处:《应用化学》2000年第1期66-68,共3页Chinese Journal of Applied Chemistry

摘  要:The N alkyl chitosans were prepared from chitosan through Schiff base formation and hydrogenation. The adsorption properties of N alkyl chitosans, bearing the same substitution degree but different carbon chain length and vice versa for Cu(Ⅱ), Hg(Ⅱ) and Pb(Ⅱ) have been investigated. It is found that chitosan derivatives of the same carbon chain length show the highest adsorption capacity for tested ions, when their substitution degree is ranged in 0 35~0 39. And among the chitosan derivatives bearing the same substitution degree, N pentyl chitosan shows the highest adsorption capacity towards mentioned ions.The N alkyl chitosans were prepared from chitosan through Schiff base formation and hydrogenation. The adsorption properties of N alkyl chitosans, bearing the same substitution degree but different carbon chain length and vice versa for Cu(Ⅱ), Hg(Ⅱ) and Pb(Ⅱ) have been investigated. It is found that chitosan derivatives of the same carbon chain length show the highest adsorption capacity for tested ions, when their substitution degree is ranged in 0 35~0 39. And among the chitosan derivatives bearing the same substitution degree, N pentyl chitosan shows the highest adsorption capacity towards mentioned ions.

关 键 词:壳聚糖 N-烷基衍生物 合成 阳离子吸附性能 

分 类 号:O636.12[理学—高分子化学] O647.31[理学—化学]

 

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