低硫可膨胀石墨制备新工艺  

A New Technology for Preparation of Low Surphur Expandable Graphite

作　　者：王慎敏[1] 周群[1] 乔英杰 

机构地区：[1]哈尔滨理工大学应用科学学院,哈尔滨150080

出　　处：《应用化学》2000年第1期93-95,共3页Chinese Journal of Applied Chemistry

基　　金：黑龙江省自然科学基金!项目;哈尔滨市学科后备带头人基金!项目 ( 9872 2 1 80 2 3)

摘　　要：A new technology including semisolid phase maceration for preparation of low surphur expandable graphite is presented, in which potassium permanganate and concentrated sulphuric acid are adopted as blended oxidants and ferric trichloride as an inserting agent. The optimum conditions of the process are as follows: mass ratio of graphite to sulfuric acid, potassium permanganate and ferric trichloride=1 03 00 80 2; reaction temperature and time: 50 ℃ and 1 h . The expandable graphite has an expanded volume of 230 mL/g and S content of 0 48%. By treating the product with sucrose borate solution and heating the flexible graphite plates also have been obtained with tensile strength of 7 5 MPa and oxidation loss of 11%. It is a green technology.A new technology including semisolid phase maceration for preparation of low surphur expandable graphite is presented, in which potassium permanganate and concentrated sulphuric acid are adopted as blended oxidants and ferric trichloride as an inserting agent. The optimum conditions of the process are as follows: mass ratio of graphite to sulfuric acid, potassium permanganate and ferric trichloride=1 03 00 80 2; reaction temperature and time: 50 ℃ and 1 h . The expandable graphite has an expanded volume of 230 mL/g and S content of 0 48%. By treating the product with sucrose borate solution and heating the flexible graphite plates also have been obtained with tensile strength of 7 5 MPa and oxidation loss of 11%. It is a green technology.

关 键 词：低硫可膨胀石墨 密封材料 制备工艺 性能 

分 类 号：O613.71[理学—无机化学]