污水处理工艺中雌激素活性分布与去除途径分析  

Analysis of the distribution and removal pathways of estrogenicity during wastewater treatment processes

作　　者：文刚[1] 邵晓玲[1] 马军[1] 

机构地区：[1]哈尔滨工业大学城市水资源与水环境国家重点实验室,城市水资源开发利用(北方)国家工程研究中心,哈尔滨150090

出　　处：《哈尔滨工业大学学报》2012年第2期94-98,共5页Journal of Harbin Institute of Technology

基　　金：城市水资源与水环境国家重点实验室(哈尔滨工业大学)自主课题(2010DX10);有机污染物的催化氧化组合技术与工艺研究(2009ZX07424-005);季节性重污染河流水源水质处理关键技术研究与示范(2009ZX07424-006)

摘　　要：针对内分泌干扰物在水中质量浓度低、危害大、去除困难的现状,采用固相萃取/重组酵母法调查了城市污水厂各工艺过程中雌激素活性的分布并对其去除途径进行分析.结果表明:雌激素活性主要存在于液相中,悬浮态中只占7.7%±5.5%;雌激素活性的去除主要发生在二级生物处理过程,通过对二级生物处理过程进行质量衡算发现,吸附到剩余污泥中的雌激素活性占进水中的1.2%,对雌激素活性的去除主要依靠微生物降解(占73.9%).通过理论计算证实雌激素活性的去除途径主要是依靠微生物降解作用,通过污泥吸附和挥发去除非常有限(小于15%).总之,城市污水厂出水中雌激素活性仍然较高(3.37～6.76 ng.L-1),强化二级生物处理或者对污水深度处理迫在眉睫.Endocrine disrupter chemicals （EDCs）, with the characterization of low concentration, high toxicity, difficulty in removal from water, are receiving more and more attentions all over the world. The current study in- vestigated the distribution of estrogenicity during wastewater treatment processes in Harbin using solid phase ex- traction/recombinant yeast system and analyzed the removal pathways of estrogenicity according to the results. Results showed that most of estrogenicity was distributed to liquid phase, whereas only （7.7 ＋_5.5） % of total estrogenicity was in the solid phase; it was also found that the secondary bio-process played a crucial role in the removal of estrogenicity, where the removal of estrogenicity took place mainly by biodegradation （73.9 % ） , whereas only 1.2 % was made through residual sludge adsorption. Last but not least, by calcu- lating the removal of estrogenieity, it confirmed that less than 15 % of estrogenicity was removed through volat- ilization and adsorption, but mainly by biodegradation. Anyway, the estrogenicity of wastewater treatment plant effluent is still high（3.37 -6.76 ng L-1）, so that the enhanced biotreatment processes or advanced treatment processes are desired to decrease the risk of estrogenieity.

关 键 词：城市污水厂 酵母双杂交法 雌激素活性 分布 去除途径 

分 类 号：X703[环境科学与工程—环境工程]